Li80Ba39N9: the first Li/Ba subnitride |
| |
Authors: | Smetana Volodymyr Babizhetskyy Volodymyr Vajenine Grigori V Simon Arndt |
| |
Institution: | Max-Planck-Institut für Festk?rperforschung, Heisenbergstrasse 1, D-70569 Stuttgart, Germany. |
| |
Abstract: | The crystal structure of Li80Ba39N9, a new representative of alkali-alkaline-earth metal subnitrides prepared from the metals and barium azide, was investigated based on single-crystal X-ray diffraction data. The compound has a novel crystal structure with a tetragonal unit cell, space group I(-)42m, a = 16.0763(8) A, c = 32.267(2) A, Z = 2, and V = 8330.0(8) A3. The structure can be described in terms of subnitride clusters with internal ionic bonding and metallic bonding in the rest of the space. The compound contains a new cluster Li12Ba5N6 and polytetrahedral Li clusters based on centered Li13 icosahedra, which are typical for Li-rich intermetallic compounds. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|