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| 新的二[4-对甲基苯基-3，5-二(2-吡啶基)-1，2，4-三氮唑]双硫氰根合锰配合物的合成，晶体结构和磁性(英) | |
| 引用本文： | 朱敦如,王天维,仲盛来,许 岩,游效曾.新的二[4-对甲基苯基-3，5-二(2-吡啶基)-1，2，4-三氮唑]双硫氰根合锰配合物的合成，晶体结构和磁性(英)[J].无机化学学报,2004,20(5):508-512. |
| 作者姓名： | 朱敦如 王天维 仲盛来 许 岩 游效曾 |
| 作者单位： | 1. 南京工业大学化学化工学院,南京,210009;南京大学配位化学国家重点实验室,配位化学研究所,南京,210093 2. 南京大学配位化学国家重点实验室,配位化学研究所,南京,210093 3. 南京工业大学化学化工学院,南京,210009 |
| 基金项目： | 南京工业大学科研启动基金资助项目。 |
| 摘 要： | 本文合成了一个新的含有4-对甲基苯基-3，5-二(2-吡啶基)-1，2，4-三氮唑配体(L)的锰(Ⅱ)配合物，MnL2(NCS)2]。其结构由X射线晶体学，红外和电喷雾离子质谱表征。在晶体结构中, 锰原子有一反演中心并由2个三芳基三氮唑配体的4个氮原子和2个反式硫氰根的2个氮原子八面体配位。磁性测定表明在75～300 K的温度范围内该配合物是顺磁性的。 |
| 关 键 词： | 锰配合物 晶体结构 电喷雾离子质谱 三氮唑 |
Synthesis, Crystal Structure and Magnetic Property of a Novel Manganese Complex [MnL2(NCS)2] [L=4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole] |
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| ZHU Dun-Ru,WANG Tian-Wei,ZHONG Sheng-Lai,XU Yan and YOU Xiao-Zeng.Synthesis, Crystal Structure and Magnetic Property of a Novel Manganese Complex [MnL2(NCS)2] [L=4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole][J].Chinese Journal of Inorganic Chemistry,2004,20(5):508-512. | |
| Authors: | ZHU Dun-Ru WANG Tian-Wei ZHONG Sheng-Lai XU Yan and YOU Xiao-Zeng |
| Institution: | College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009;Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
| Abstract: | A novel manganese(Ⅱ) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (L), MnL2(NCS)2],has been synthesized and its structure characterized by X-ray crystallography,FT-IR and ESI-MS spectroscopy.In the structure there is an inversion center at the manganese(Ⅱ) atom which is octahedrally coordinated to four nitrogen atoms from two triaryltriazole ligands (L) and nitrogen atoms of two NCS- ions in a trans arrangement.Magnetic measurements show that the complex is high-spin species in the 75～300 K range. CCDC: 234894. |
| Keywords: | Manganese(Ⅱ) complex crystal structure ESI-MS spectra triazole |
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