Synthesis,Crystal Structure,and Properties of Mixed Salt Cs2SO4 · H6TeO6 |
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| Authors: | Romanchenko E V Shilov G V Dobrovolskii Yu A Karelin A I Atovmyan L O |
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| Institution: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia |
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| Abstract: | Mixed salt Cs2SO4 · H6TeO6 (I) is synthesized and its structure and properties are studied by X-ray diffraction analysis, IR and Raman spectroscopies, impedance measurements, and differential thermal analysis. Compound I crystallizes in hexagonal system with unit cell parameters a = 7.455(1) Å, c = 33.303(7) Å, space group R3c, Z = 6. Its crystal structure consists of the H6TeO6 molecules and SO4
2- anions united by network of hydrogen bonds and Cs+ cations. |
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