Investigation of the reaction of Br
2
-
and Fe(II) using laser pulsed photolysis |
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Authors: | I V Khmelinskii V F Plyusnin V P Grivin |
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Institution: | (1) Institute of Chemical Kinetics and Combustion, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk |
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Abstract: | Conclusions The reaction of Br
2
-
with Fe
solv
2+
in a mixture of methanol with diethyl ether occurs according to a intrasphere mechanism with the primary product being the FeBr2+ complex. The rate constant (5.9 ± 0.5)-107 dm3/mole·sec at 298 K is greater by a factor of 15–20 than in the reaction of Br
2
-
with Fe
aq
2+
, despite the slower rate of exchange of the solvent molecules for Fe
2
-
. In the latter case the reduced permittivity considerably increases the lifetime of partners in the contact pair state.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1247–1250, June, 1988. |
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Keywords: | |
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