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Conformational peculiarities of a new heterocyclic dihydrothienothiopyranoisoxazole system
Authors:M. M. Krayushkin  L. G. Vorontsova  M. G. Kurella  E. Yu. Zvezdina  M. A. Kalik
Affiliation:(1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation
Abstract:The crystalline and molecular structures of 3H-3a,4-dihydro-7-methylthieno[3prime,2prime:5,6]thiopyrano[4,3-c]isoxazole and 3H-3a,4-dihydro-3-isopropoxycarbonyl-3a,7-dimethylthieno[3prime,2prime:5,6]thiopyrano[4,3-c]isoxazole are determined by X-ray analysis. The effect of steric factors on intramolecular 1,3-dipolar cycloaddition is shown.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 302–304, February, 1995.This work was financially supported by the Russian Foundation for Basic Research (Project No. 93-03-18461).
Keywords:3H-3a,4-dihydro-7-methylthieno[3  /content/m6013246lq36x780/xxlarge8242.gif"   alt="  prime"   align="  BASELINE"   BORDER="  0"  >,2  /content/m6013246lq36x780/xxlarge8242.gif"   alt="  prime"   align="  BASELINE"   BORDER="  0"  >:5,6]thiopyrano[4,3-c]isoxazole  3H-3a,4-dihydro-3-isopropoxycarbonyl-3a,7-dimethylthieno[3  /content/m6013246lq36x780/xxlarge8242.gif"   alt="  prime"   align="  BASELINE"   BORDER="  0"  >,2  /content/m6013246lq36x780/xxlarge8242.gif"   alt="  prime"   align="  BASELINE"   BORDER="  0"  >:5,6]thiopyrano-[4,3-c]isoxazole  X-ray analysis  conformation
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