| Synthesis and characterization of a new Mo-Fe-S cluster compound containing MoO_3S_3 unit and mixed-valent Mo atoms [Et_4N]_2[Mo_2Fe(CO)_4(S,O-C_6H_4-1,2)_3Cl_2] |
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| 作者姓名： | ZHUANG Bo-Tao LAN An-Jian HE Ling-Jie HUANG Liang-RenFujian Institute of Research on the Structure of Matter Chinese Academy of Sciences State Key Laboratory of Structural Chemistry Fuzhou Fujian China |
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| 作者单位： | ZHUANG，Bo-Tao LAN，An-Jian HE，Ling-Jie HUANG，Liang-RenFujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry，Fuzhou，Fujian 350002，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China. |
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| 摘 要： | Reaction of Mo3(CO)7(S,O-C6H4-1,2)3]2- with FeCl2 in MeCN at 60℃ affords a new Mo-Fe-S cluster complex containing MoO3S3 unit and mixed-valeut Mo atoms, Et4N]2Mo2Fe-(CO)4(O,S-C6H4-1,2)aCl2] (1). 1 is characterized by elemental analysis, IR, Mossbauer spectra, X-ray photoelectron spectra and mass spectra. And the structure of 1 is suggested as the structure which contains a Mo(S,O-C6H4-1,2)3] unit of which the two of three sulfur atoms link to a Mo(CO)4-moiety and the three oxygen atoms are coordinated to a FeCl2 ligand.
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Synthesis and characterization of a new Mo-Fe-S cluster compound containing MoO_3S_3 unit and mixed-valent Mo atoms [Et_4N]_2[Mo_2Fe(CO)_4(S,O-C_6H_4-1,2)_3Cl_2] |
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| ZHUANG,Bo-Tao LAN,An-Jian HE,Ling-Jie HUANG,Liang-RenFujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,State Key Laboratory of Structural Chemistry,Fuzhou,Fujian ,China.Synthesis and characterization of a new Mo-Fe-S cluster compound containing MoO_3S_3 unit and mixed-valent Mo atoms [Et_4N]_2[Mo_2Fe(CO)_4(S,O-C_6H_4-1,2)_3Cl_2][J].Chinese Journal of Chemistry,1994,12(6):495-502. |
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| Authors: | ZHUANG Bo-Tao LAN An-Jian HE Ling-Jie HUANG Liang-RenFujian Institute of Research on the Structure of Matter Chinese Academy of Sciences State Key Laboratory of Structural Chemistry Fuzhou Fujian China |
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| Institution: | ZHUANG,Bo-Tao LAN,An-Jian HE,Ling-Jie HUANG,Liang-RenFujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,State Key Laboratory of Structural Chemistry,Fuzhou,Fujian 350002,China |
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| Abstract: | |
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| Keywords: | Synthesis characterization Mo-Fe-S cluster MoO3S3 unit mixed-valence |
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