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聚芳醚亚砜的合成与表征
引用本文:刘鸿,刘晓玲,程彩霞,宋才生. 聚芳醚亚砜的合成与表征[J]. 高分子学报, 2002, 0(1): 43-46
作者姓名:刘鸿  刘晓玲  程彩霞  宋才生
作者单位:江西师范大学化学与生物科学学院,南昌,330027
摘    要:以二苯醚和二氯亚砜为主要单体 ,在无水AlCl3/CH2 ClCH2 Cl/NMP催化剂溶剂体系中进行低温溶液共聚 ,合成聚芳醚亚砜 (PPOS) ,研究了AlCl3/NMP用量及单体摩尔比对聚合反应的影响 .用IR、DSC、TG和X ray等对PPOS进行结构和性能的分析与表征 ,研究结果表明 :PPOS属无定形聚合物 ,具有较高的玻璃化转变温度 (Tg) ,软化温度在 2 6 0℃左右 ,在加热过程中出现二个热分解温度

关 键 词:聚芳醚亚砜  二苯醚  二氯亚砜  低温溶液缩聚
修稿时间:2001-03-23

SYNTHESIS AND CHARACTERIZATION OF POLYAROMATIC ETHER SULFOXIDE
LIU Hong,LIU Xiaoling,CHENG Caixia,SONG Caisheng. SYNTHESIS AND CHARACTERIZATION OF POLYAROMATIC ETHER SULFOXIDE[J]. Acta Polymerica Sinica, 2002, 0(1): 43-46
Authors:LIU Hong  LIU Xiaoling  CHENG Caixia  SONG Caisheng
Abstract:Polyaromatic ether sulfoxides were prepared by low temperature solution copolymerization of diphenyl ehter with thionyl chloride in the presence of aluminum chloride 1,2 dichloroethane and N methylpyrrolidone.The effect of using N methylpyrrol idone with aluminum chloride and mole ratio of monomers upon polymerizaton reation was investigated.Properties of polymers were characterised by IR,DSC,TG,X ray diffraction etc. The results showed that these polymers didn't crystallize but had a high glass transition temperature ( T g).The softening temperature was about 260℃ and there were two decomposition temperatures in the dynamic thermogravimetry.
Keywords:Polyaromatic ether sulfoxides   Diphenyl ether   Thionyl chloride   Low temperature solution   Copolymerization
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