Hydrogen storage using polymer-supported organometallic dihydrogen complexes: a mechanistic study |
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| Authors: | Cooper Andrew I Poliakoff Martyn |
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| Institution: | Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK. aicooper@liv.ac.uk |
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| Abstract: | The dihydrogen complex W(CO)(5)(H(2)) can be both generated and dissociated in polymer matrices by UV photolysis at 220 K and 90 K, respectively, suggesting a potential "UV-activated" mechanism for hydrogen storage and release. |
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