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Concerted attack of frustrated Lewis acid-base pairs on olefinic double bonds: a theoretical study
Authors:Stirling András  Hamza Andrea  Rokob Tibor András  Pápai Imre
Affiliation:Chemical Research Center of HAS, Pusztaszeri út 59-67, H-1025 Budapest, Hungary.
Abstract:A computational approach reveals cooperative action of the preorganized acidic and basic centers of the frustrated P(t-Bu)(3)/B(C(6)F(5))(3) Lewis pair on olefinic bonds as the key to the observed regioselective addition reaction.
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