Synthesis and characterization of tris(2-pyridylthio)methanido Zn complex with a Zn-C bond and DFT calculation of its one-electron oxidized species |
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| Authors: | Kitano Ken'ichi Kuwamura Naoto Tanaka Rika Santo Ryoko Nishioka Takanori Ichimura Akio Kinoshita Isamu |
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| Institution: | Department of Material Science and Chemistry, Osaka City University, Sumiyoshi-ku, Osaka, Japan. |
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| Abstract: | Tris(2-pyridylthio)methane (tptmH) reacts with ZnCl(2) producing the Zn-C containing complex of ZnCl(tptm)], whose cyclic voltammogram shows an irreversible oxidation peak at 0.2 V vs. E(0')(Fc(+/0)). DFT calculations suggested that 1e(-) oxidation should occur at the tptm ligand resulting in the cleavage of the Zn-C bond, leading to decomposition of the complex. |
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