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Chiral binuclear copper(II) catalyzed nitroaldol reaction: scope and mechanism |
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| Authors: | Suribabu Jammi |
| Institution: | Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India |
| Abstract: | Chiral binuclear copper(II) Schiff base complexes 4a-g have been prepared from aldehydes 1a,b, (S)-amino alcohols 2a-f, and Cu(OAc)2·1H2O in high yield. Their catalysis is studied for the addition of nitroalkanes to aldehydes at ambient conditions with 76:24 er. |
| Keywords: | Binuclear copper(II) complex Bifunctional catalyst Homogeneous process Nitroaldol reaction Aldehydes Nitroalkanes |
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