Enantioselective synthesis of martinelline chiral core and its diastereomer using asymmetric tandem Michael-aldol reaction |
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| Authors: | Yayoi Yoshitomi |
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| Institution: | Graduate School of Pharmaceutical Sciences, Chiba University, Yayoi-cho, Inage-ku, Chiba 263-8522, Japan |
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| Abstract: | The martinelline chiral core 3 and its diastereomer were synthesized by using the asymmetric tandem Michael-aldol reaction as the key step from 4-methoxycarbonylanthranilaldehyde and the α,β-unsaturated aldehyde. |
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| Keywords: | Martinelline Martinellic acid Tandem Michael-aldol reaction Organocatalyst Asymmetric synthesis |
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