低能氮离子对胞嘧啶水溶液损伤作用的光谱分析

利用N2常压弧光放电产生低能N^ ,经电场加速后注入胞嘧啶（C）水溶液,研究了低能N^ 作用后胞嘧啶水溶液的紫外及红外吸收光谱的变化。结果表明,低能N^ 对溶液样品造成成了多种形式的损伤,形成丰富多彩的损伤产物,其中不仅包括水溶液中多种损伤碎片之间的重新化合,还包括N^ 与溶液中元素形成新的化学基团,继而与其他碎片结合形成产物,使外来的N^ “沉积”在溶液样品中。

Analysis of the Spectrum of Damage Effects of Low Energy N+ Ions on Cytosine Aqueous Solution

Low energy N+ ions were produced by gas arc-discharge and the ions were accelerated into cytosine (C) aqueous solution. Changes in UV and infrared spectra of C after this kind of ions' action were investigated. UV spectra showed that absorption at 259 nm gradually decreased and lambda max of C solution moved toward the longer wavelength with the time. Thus, it was deduced that C was damaged and some fragments including -NO2 and -NH2 groups might have been produced. Judging from the IR spectra, the disappearance of the peak of 3,005 cm-1 confirmed the formation of -NO2 groups. All these results revealed that N+ ions caused various damages on C molecules and many new substances were formed. These new substances were not synthesized only by combination of the damage fragments in the solution, but also by "deposition" of N+ from outside.