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A charge-transfer host system composed of a chiral 1,1′-bi-2-naphthol cluster and benzylviologen |
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| Authors: | Yoshitane Imai Kensaku Kamon Nobuo Tajima Reiko Kuroda Yoshio Matsubara |
| Institution: | a Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka 577-8502, Japan b First-Principles Simulation Group, Computational Materials Science Center, NIMS, Sengen, Tsukuba, Ibaraki, 305-0047, Japan c JST ERATO-SORST Kuroda Chiromorphology Team, 4-7-6 Komaba, Meguro-ku, Tokyo, 153-0041, Japan d Department of Life Sciences, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo, 153-8902, Japan |
| Abstract: | Chiral charge-transfer (CT) complexes composed of a chiral 1,1′-bi-2-naphthol cluster as the electron donor and 1,1′-dibenzyl-4,4′-bipyridinium dichloride as the electron acceptor serve as a host system for molecular recognition. CT complexes that include guest alcohols show different diffuse reflectance spectra (DRS) depending on the included guest. |
| Keywords: | 1 1&prime -Bi-2-naphthol cluster Chiral CT complex Molecular recognition Solid-state host system Viologen |
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