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A New Copper(I) Coordination Polymer with N2-Donor Schiff Base and Its Use as Precursor for CuO Nanoparticle: Spectroscopic,Thermal and Structural Studies |
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| Authors: | Aliakbar Dehno Khalaji Jan Rohlicek Pavel Machek Debasis Das |
| Institution: | 1. Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran 2. Institute of Physics of the ASCR, v.v.i., Na Slovance 2, 182 21, Prague 8, Czech Republic 3. Department of Chemistry, The University of Burdwan, Burdwan, West Bengal, India |
| Abstract: | A new copper(I) coordination polymer, Cu((3,4-MeO-ba)2bn)I]n (1), using a bridging Schiff base ligand, N,N′-bis(3,4-dimethoxybenzylidene)butane-1,4-diamine, (3,4-MeO-ba)2bn, containing a flexible spacer (=N–CH2–CH2–CH2–CH2–N=) has been synthesized and characterized by elemental analyses (CHN) and FTIR spectroscopy, thermal analysis and powder X-ray structure analysis. In 1, Cu(I) ions are bridged by Schiff base ligands and iodine atoms forming 1D-chain. The thermal stability of 1 was studied by thermal gravimetric and differential thermal analyses. 1 is used to prepare CuO nanoparticles via solid state thermal decomposition in air and nanoparticles thus formed are characterized by scanning electron microscopy, transmission electron microscopy and powder X-ray diffraction techniques. |
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