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Reaction of 4-methyl-4-tribromomethylcyclohexa-2,5-dien-1-one with zinc metal
Authors:G V Gavrilova  A A Gavrilov  K P Butin
Institution:(1) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation
Abstract:4-Methyl-4-tribromomethylcyclohexa-2,5-dien-1-one reacts with zinc dust in absolute DMF to give a mixture of 4-bromo-5-methylcyclohepta-2,4,6-trien-1-one, 4-methyl-cyclohepta-2,4,6-trien-1-one, and 4-dibromomethyl-4-methylcyclohexa-2,5-dien-1-one. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 177–178, January, 1998.
Keywords:4-methyl-4-tribromomethylcyclohexa-2  5-dien-1-one  reaction with zinc metal  4-bromo-5-methyltropone  4-methyltropone  mechanism of formation
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