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Synthesis of oxime phosphoranes from reaction between triphenylphosphine and acetylenic esters in the presence of oxime derivatives
Authors:Malek Taher Maghsoodlou  Sayyed Mostafa Habibi-Khorassani  Reza Heydari  Asadollah Hassankhani  Ghasem Marandi  Mahmoud Nassiri  Elaheh Mosaddeg
Affiliation:(1) Department of Chemistry, University of Sistan and Balouchestan, 98135–674 Zahedan, Iran
Abstract:A new one-pot, simple and effective procedure is presented for the preparation of O-containing phosphorus ylides by the Michael addition reaction of N-methylpyrrole-2-carbaldehydoxime, pyridin-2-carbaldehydoxime or acetophenonoxime with acetylenic esters.
Keywords:Stable phosphorus ylides  Michael addition   N-methylpyrrole-2-carbaldehydoxime  Pyridin-2-carbaldehydoxime and acetophenonoxime  Rotational isomers
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