Dynamic thermogravimetric degradation of gamma radiolytically synthesized Ag–PVA nanocomposites |
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Authors: | AN Krklje MT Marinovi-Cincovi ZM Ka
arevi-Popovi JM Nedeljkovi |
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Institution: | aVinča Institute of Nuclear Sciences, Mike Petrovića Alasa 12-14, 11001 Belgrade, Serbia |
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Abstract: | The degradation kinetics of gamma radiolytically synthesized Ag–PVA nanocomposites was investigated by thermogravimetric method under dynamic conditions (30–600 °C) in an inert atmosphere. Thermogravimetric analysis showed that thermal degradation of composites was a two-stage process for the lower amount of nanofiller and single-stage for the higher amount of nanofiller. The Vyazovkin model-free kinetics method was applied to calculate the activation energy (Ea) of the degradation process as a function of conversion and temperature. At a given degradation temperature, PVA as a host in nanocomposite presents lower reaction velocity, while its Ea is higher than that of pure PVA. |
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Keywords: | Ag–PVA nanocomposites Gamma irradiation Dynamic thermogravimetric analysis Model-free kinetics |
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