Jacobsen Enantioselective Hydrolysis of Glycidyl Diethyl Phosphate |
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| Authors: | Z A Bredikhina V G Novikova A A Bredikhin |
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| Institution: | (1) Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia |
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| Abstract: | Scalemic diethyl phosphates of glycerol and glycidol were prepared by partial enantioselective hydrolysis of racemic glycidyl diethyl phosphate in the presence of chiral Co(salen) catalyst. The enantiomeric composition of the products was analyzed by 31P NMR spectroscopy with organophosphorus reagents. |
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