| Synthesis of Novel Cyclic Aryl Ether Thioether Ketone (Sulfone) Oligomers |
| |
| 作者姓名： | Ying Hua QI Tian Lu CHEN Hong Yan JIANG Hai Bo LI Ji Ping XU |
| |
| 作者单位： | Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022 |
| |
| 摘 要： | Thering-openingpolymerization(ROP)reactionplaysanimportantroIeinproductionofhigh-performancethermoplastics'.ThecyclicoligomersofferauniquecombinationoflowmeltviscosityandthecapabilityofachievingveryhighmolecuIarweightinashortreactiontimewithoutthereleaseofvolatilebyproductsandROPhasbeenanactivesubjectofindustrialandacademicresearch.TheROPsofmanycyclicoligomershavebeenachievedviaanionicpolymerizationinthepresenceofthenucleophilicinitiatorsuchascaesiumfluorideandalkaliphenoxides',butusingthe…
|
Synthesis of Novel Cyclic Aryl Ether Thioether Ketone (Sulfone) Oligomers |
| |
| Ying Hua QI, Tian Lu CHEN, Hong Yan JIANG, Hai Bo LI, Ji Ping XU.Synthesis of Novel Cyclic Aryl Ether Thioether Ketone (Sulfone) Oligomers[J].Chinese Chemical Letters,1998(7). |
| |
| Authors: | Ying Hua QI Tian Lu CHEN Hong Yan JIANG Hai Bo LI Ji Ping XU |
| |
| Abstract: | Two kinds of macrocyc1ic oligomers containing aromatic sulfide linkages have been synthesized by the solution polycondensation in high yield. The cyclic compounds were characterized by 1H and 13C NMR, by and MALDI -TOF MS. |
| |
| Keywords: | Cyclic aryl ether thioether ketone (sulfone) oligomers Free radical ROP MALDI |
| 本文献已被 CNKI 等数据库收录！ |
