Kinetic processes of Hg6s6p(P1) in xenon |
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| Authors: | Anthony B Callear and Kangyan Du |
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| Institution: | Physical Chemistry Department, University of Cambridge, Cambridge CB2 IEP, UK |
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| Abstract: | The principal route for decay of Hg 6s6p(3P1) in xenon is shown to be bimolecular deactivation to the mercury ground state, with rate coefficient 9.1 × 10?13 cm3 molecule?1 s?1; relaxation to the 3P0 state plays a negligible role. The equilibrium constant of the reaction Hg(3P1) + Xe  HgXe(A 3O+), has been recorded as 1.73 × 10?20 cm3 molecule?1 at 293 K. |
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