| Abstract: | With the aid of the non-steady-state kinetic method, the sequence distribution of polydienes conforming to a Bernoullian process is treated theoretically. The expressions for sequence length distribution, the probability functions, and other structural parameters are derived in closed form. The results obtained show that at the beginning of polymerization all the parameters mentioned vary with reaction time, monomer conversion, and the ratio of initial concentrations of monomer to initiator, but monotropically approach their respective limits which are identical with those derived from statistics. |
