Time-resolved vibrational chemiluminescence: Rate constants for the reactions of F atoms with H2O and HCN,and for the relaxation of HF (v = 1) by H2O and HCN |
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| Authors: | Robert J. Frost David S. Green Martin K. Osborn Ian W. M. Smith |
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| Abstract: | Rate constants have been determined at (298 ± 4) K for the reactions:  and the relaxation processes:  Time-resolved HF(1,0) emission was observed following the photolysis of F2 with pulses from an excimer laser operating on XeCl (λ = 308 nm). Analysis of the emission traces gave first-order constants for reaction and relaxation, and their dependence on [H2O] and [HCN] yielded:     |
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