首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Advantage of the universal equation over the linear equation for the calculation of retention parameters of homologous series in capillary chromatography
Authors:N I Svetlova  A L Samusenko  R V Golovnya
Abstract:A procedure is suggested for preparation of reproducible and stable galss capillary Apiezon LH+KF columns for the determination of organic compounds containing different functional groups. The advantage of the universal equation over the linear equation for calculation of retention indices for any homologs, including the first members of the series, is shown using the following five homologous series as examples: fatty acid methyl esters, methyl ketones, secondary and tertiary aliphatic amines, and N-alkyl piperidines. The accuracy of the calculation enables the universal equation to be used in computer-assisted identification.
Keywords:Gas chromatography  GC  Glass capillary columns  Retention parameters  Universal equation
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号