Abstract: | Several derivatives of secondary perfluoroalkyl iodides such as CF3CFI(CF2)2O(CF2)3SO2F (3), CF3CFI(CF2),O(CF2)2SO3Na (4), CF3CFI(CF3)n Cl (n=2, 7a; n=4, 7b) and CF3(CF2)2-OCFICF3 (8) were synthesized using known methods, their reaction with sodium dithionite was studied and various olefins were added into the reaction system as radical traps to yield the 1:1 radical adducts. |