Pd(0)/Au(I) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(I)-complexes |
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| Authors: | Weber Dieter Gagné Michel R |
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| Affiliation: | Caudill Laboratories, Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-3290, USA. |
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| Abstract: | A Pd(II)-catalyzed homo-coupling of Au(I)-aryls is reported. The reaction is driven by a Pd(0)/Au(I) redox reaction that generates a gold mirror and Pd(II), and illustrates one of the challenges for developing dual catalytic Au-Pd systems. |
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