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Facile synthesis of metal N-heterocyclic carbene complexes
Authors:Liu Bin  Zhang Yin  Xu Daichao  Chen Wanzhi
Affiliation:Department of Chemistry, Zhejiang University, Xixi Campus, Hangzhou, 310028, China.
Abstract:A novel electrochemical procedure for the preparation of metal complexes of N-heterocyclic carbenes using imidazolium salts or corresponding silver-NHC complexes as carbene sources and electrolytes, and metal plates as the sacrificial anodes is described. The procedure is simple and good yielding without the use of expensive or air-sensitive reagents.
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