Confined polymer melts studied by atomic force microscopy |
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Authors: | Gexiao Sun, Michael Kappl,Hans-Jü rgen Butt, |
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Affiliation: | Max-Planck-Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany |
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Abstract: | Using an atomic force microscope (AFM) the interaction between an AFM tip and different planar solid surfaces have been measured across a long-chain poly(dimethyl siloxane) (PDMS, MW = 18,000 g/mol), a short-chain PDMS (MW = 4200 g/mol), a poly(ethylmethyl siloxane) (PEMS, MW = 16,800 g/mol), and a diblock copolymer consisting of one PDMS and one PEMS block (PDMS-b-PEMS, MW = 15,100 g/mol). The interaction changed significantly during the first 10 h after immersing the solids in the polymer melt. This demonstrates that the time scale of structural changes at a solid surface is much slower than in the bulk. On mica and silicon oxide both polymers formed an immobilized “pinned” layer beyond which a monotonically decaying repulsive force was observed. Attractive forces were observed with short-chain PDMS on silicon oxide and PEMS on mica and silicon oxide. On the basal plane of graphite PEMS caused a stable, exponentially decaying oscillatory force. |
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Keywords: | AFM Block copolymer Composite material PDMS Surface force |
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