Cu3AlCl6 und Cu2Al2Cl8, die Gaskomplexe im System CuCl/Al2Cl6 |
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Authors: | Harald Sch fer,Helmut Rabeneck |
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Affiliation: | Harald Schäfer,Helmut Rabeneck |
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Abstract: | Cu3AlCl6 and Cu2Al2Cl8, Gas Complexes in the System CuCl/Al2Cl6 Investigations by mass spectroscopy in the system CuCls/Al2Cl6,gestablished that only Cu3AlCl6 and Cu2Al2Cl8 are observed as principal gas complexes. Results of flow measurements published by LAUGHLIN and Gregory (1976) which were attributed erroneously by these authors to the complex CuAlCl4 may be described by the equilibria given in “Inhaltsübersicht”. The complexes cu3AlCl6 and Cu2Al2Cl8 are supposed to have a cube type structure similar to Cu4Cl4. |
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