Die Kristallstruktur des Dodekamethyl-hexasila-tetraphospha-adamantans (Sime2)6P4 |
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| Authors: | Wolfgang Hnle Hans Georg von Schnering |
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| Institution: | Wolfgang Hönle,Hans Georg von Schnering |
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| Abstract: | Crystal Structure of Dodecamethyl-hexasila-tetraphospha-adamantane (Sime2)6P4 Dodecamethyl-hexasila-tetraphospha-adamantane (Sime2)6P4 crystallizes in the cubic space group I 4 3m with a = 1081.7 pm and Z = 2 formula units. The bond lengths are P? Si = 224.9 pm, C? Si = 186.4 pm and C? H = 87 pm. The bond angles at the P-atoms are 104.4° and at the Si-atoms 118.8°. – The structure of the isotypic compound (Geme2)6P4 was refined. |
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