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Electrochemical synthesis of niobium compounds in anodic dissolution of ferroniobium in methanol
Authors:M Yu Berezkin  E G Polyakov  V V Turygin  L V Kaabak  A V Khudenko  A P Tomilov
Institution:(1) State Research Institute of Organic Chemistry and Technology, Federal State Unitary Enterprise, Moscow, Russia;(2) St. Petersburg State Polytechnic University, St. Petersburg, Russia
Abstract:Anodic dissolution of ferroniobium in anhydrous methanol in the presence of sodium methylate was studied. The possibility of recovering pure hexamethoxyniobate from the electrolyzate and its conversion into niobium methylate with an iron content not exceeding 0.01% was analyzed.
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