Synthesis and characterization of some novel cyanonitrosyl complexes of chromium(I) with Mannich bases,aromatic aldehyde oximes and syn-phenyl-2-pyridylketoxime |
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| Authors: | Ram C Maurya Deen D Mishra Surendra K Jaiswal Sudipta Mukherjee |
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| Institution: | 1. Coordination Chemistry Laboratory, Department of P.G. Studies and Research in Chemistry, R.D. University, 482 001, Jabalpur, India
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| Abstract: | Some new low-spin hexacoordinated cyanonitrosyl complexes of Cr1 of the type Cr(NO)(CN)2(L)2(H2)], where L is an aromatic aldehyde oxime or Mannich base, have been prepared by the interaction or K3Cr(NO)(CN)5]· H2O with L in aqueous AcOH, and characterized by a range of physico-chemical techniques, I.r. data suggest that all the oxime
derivatives and Mannich bases act as monodentate ligands by coordinating through the aromatic nitrogen.
TMC 2564 |
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