Strong magnetic interactions through weak bonding interactions in organometallic radicals: combined experimental and theoretical study |
| |
Authors: | Cauchy Thomas Ruiz Eliseo Jeannin Olivier Nomura Mitsushiro Fourmigué Marc |
| |
Institution: | Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain. |
| |
Abstract: | The magnetic properties of a series of three neutral radical organometallic complexes of general formula CpNi(dithiolene)]. have been investigated by a combination of X-ray crystal structure analysis and magnetic susceptibility measurements, while the assignment of the exchange coupling constants to the possible exchange pathways has been accomplished with the help of calculations based on density functional theory (DFT). The syntheses and X-ray structures of CpNi(adt)] (adt=acrylonitrile-2,3-dithiolate) and CpNi(tfd)] (tfd=1,2-bis(trifluoromethyl)ethene-1,2-dithiolate) complexes are described, while CpNi(mnt)] (mnt=maleonitriledithiolate) was reported earlier. In the three complexes, we observed strong antiferromagnetic coupling that could not be explained solely by short SS intermolecular contacts. Our calculations indicated that spin density in these complexes is strongly delocalized on the NiS2 moiety, with up to 20% on the Cp ring. As a consequence, CpCp and Cpdithiolene overlap interactions have been identified as responsible for antiferromagnetic couplings. The CpNi(adt)] complex thus has a value J=-369.5 cm(-1) for an exchange interaction through a pi stacking due to the CpCp overlap. |
| |
Keywords: | antiferromagnetism density functional calculations exchange interactions organometallic radicals pi stacking |
本文献已被 PubMed 等数据库收录! |
|