Unusual reaction of beta-hydroxy alpha-diazo carbonyl compounds with Cl3CCN/NaH and Rh(II)-catalyzed reaction of beta-trichloroacetylamino alpha-diazo carbonyl compounds |
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Authors: | Shi Weifeng Jiang Nan Zhang Shiwei Wu Weiming Du Daming Wang Jianbo |
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Institution: | Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871, China. |
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Abstract: | The hydroxyl group was directly converted into the trichloroacetylamino group by reacting beta-hydroxy alpha-diazo carbonyl compounds with Cl(3)CCN and NaH. Rh(II)-catalyzed reactions of the beta-amino alpha-diazo carbonyl compounds were discussed. reaction: see text] |
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