Synthesis and properties of palladium(I) carbonyl chlorides |
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| Authors: | I V Fedoseev A S Gordeev |
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| Institution: | (1) Kaluga Branch, Bauman State Technical University, Kaluga, Russia |
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| Abstract: | Palladium(I) carbonyl chloride (PdCOCl) n has been synthesized by the effect of CO on PdCl2 in the presence of trace water. Anionic palladium(I) carbonyl chloride has been synthesized during treatment of ethanol-based or acetone-based solutions of H2PdCI4 containing small amounts of water; it has been isolated from the solution as the salt Cs2Pd2(CO)2Cl4]. IR-spectra, X-ray diffraction patterns, and thermogravimetry data on synthesized palladium(I) carbonyl complexes are presented. |
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