Studies toward frondosin A and its analogues. Formal total synthesis of (+/-)-frondosin A |
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| Authors: | Li Xin Keon Alec E Sullivan Jonathan A Ovaska Timo V |
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| Affiliation: | Department of Chemistry, Connecticut College, 270 Mohegan Avenue, New London, Connecticut 06320, USA. |
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| Abstract: | Two reaction sequences commencing with different starting materials were successfully employed for the synthesis of frondosin A analogues, including (+/-)-frondosin A dimethyl ether. Construction of the bicyclo[5.4.0]undecane core in each case was achieved through an expedient microwave-assisted tandem 5-exo cyclization--Claisen rearrangement process. |
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