Oxidation of camphor ethylene dithioacetal |
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| Authors: | A V Timshina S A Rubtsova I N Alekseev P A Slepukhin A V Kuchin |
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| Institution: | (1) Advanced Photon Source, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439, USA |
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| Abstract: | (1R,1′R,2S,4R)-1,7,7-Trimethylspirobicyclo2.2.1]heptane-2,2′-1,3]dithiolane] 1′-oxide, (1R,2S,3′R,4R)-1,7,7-trimethylspirobicyclo2.2.1]heptane-2,2′-1,3]dithiolane] 1′,1′,3′-trioxide, and (1R,4R)-1,7,7-trimethylspirobicyclo2.2.1]heptane-2,2′-1,3]dithiolane] 1′,1′,3′,3′-tetraoxide were synthesized by oxidation of
camphor ethylene dithioacetal with m-chloroperoxybenzoic acid at different substrate-tooxidant ratios. The structure of the products was proved by IR and NMR
spectroscopy and X-ray analysis. |
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