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RHEOLOGICAL CHARACTERIZATION OF PROCESSABILITY OF UNVULCANIZED POLYBUTADIENE
引用本文:杜雪,许元泽,钱人元. RHEOLOGICAL CHARACTERIZATION OF PROCESSABILITY OF UNVULCANIZED POLYBUTADIENE[J]. 高分子科学, 1987, 0(1): 81-86
作者姓名:杜雪  许元泽  钱人元
作者单位:Institute of Chemistry,Academia Sinica,Beijing,Institute of Chemistry,Academia Sinica,Beijing,Institute of Chemistry,Academia Sinica,Beijing
摘    要:Rheological investigation on a series ot unvulcamzed polybutadiene elastomers of different processability has been carried out by means of a capillary extrusion rheometer. It is found that the processability of unvulcanized polybutadiene can be correlated with the occurrence of unsteady flow and the wall stress, dependence of the dimensionless number e characterizing the entrance elongational elasticity which has been found to be sensitive to the branching structure and the molecular weight distribution of the samples. Interpretations based on the structural data of unvulcanized polybutadiene were discussed.

收稿时间:1986-12-26

RHEOLOGICAL CHARACTERIZATION OF PROCESSABILITY OF UNVULCANIZED POLYBUTADIENE
DU Xue,XU Yuanze,QIAN Renyuan. RHEOLOGICAL CHARACTERIZATION OF PROCESSABILITY OF UNVULCANIZED POLYBUTADIENE[J]. Chinese Journal of Polymer Science, 1987, 0(1): 81-86
Authors:DU Xue  XU Yuanze  QIAN Renyuan
Affiliation:Institute of Chemistry; Academia Sinica; Beijing
Abstract:Rheological investigation on a series ot unvulcamzed polybutadiene elastomers of different processability has been carried out by means of a capillary extrusion rheometer. It is found that the processability of unvulcanized polybutadiene can be correlated with the occurrence of unsteady flow and the wall stress, dependence of the dimensionless number e characterizing the entrance elongational elasticity which has been found to be sensitive to the branching structure and the molecular weight distribution of the samples. Interpretations based on the structural data of unvulcanized polybutadiene were discussed.
Keywords:Rheology  Polybutadiene  Processability  Elongational elasticity
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