Synthesis of 1,2-azaphospholanes containing an amino acid fragment |
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| Authors: | O. V. Bykhovskaya I. M. Aladzheva D. I. Lobanov P. V. Petrovskii K. A. Lyssenko I. V. Fedyanin T. A. Mastryukova |
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| Affiliation: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation |
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| Abstract: | 2-Oxo-1,2-azaphospholanes and 1,2-azaphospholanium salts containing an amino acid fragment were synthesized by intramolecular P-alkylation of N-3-chloropropyl-substituted tricoordinate phosphorus amides. Hydrolysis of 2-oxo-1,2-azaphospholanes at the P-N bond gives rise to γ-aminopropylphosphonic acid derivatives. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2557–2562, November, 2005. |
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| Keywords: | P-alkylation Arbuzov rearrangement 2-oxo-1,2-azaphospholanes 1,2-azaphospholanium salts diastereomers hydrolysis γ -aminopropylphosphonic acid derivatives NMR spectroscopy X-ray diffraction study |
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