Mössbauer study of photolysis and γ-radiolysis of alkali bis(citrato) ferrates(III) |
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| Authors: | A.S. Brar B.S. Randhawa |
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| Affiliation: | Chemistry Department, Guru Nanak Dev University, Amritsar 143005, India |
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| Abstract: | The photolysis of alkali bis(citrato) ferrates(III) M3Fe(cit)2·xH2O (M = Li, Na, K, Cs, NH4) in solid and solution phases and γ-radiolysis in solid state has been investigated using Mössbauer and IR spectroscopic techniques. The formation of iron(II) species as the ultimate product in all these complexes has been observed except the solid state photolysis of potassium bis(citrato) ferrate(III) in which the intermediate iron(II) moiety is oxidized to an octahedral iron(III) species. |
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| Keywords: | Author to whom correspondence should be addressed. Present address: Chemistry Department I.I.T. New Delhi 110016 India. |
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