A novel closo-type metallaundecaborane, [1,1-(PPh3)2-2,5-(OEt)2-1-RuB10H8], and its relationship to the ‘isocloso’ series of metallaborane clusters |
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| Authors: | Janet E. Crook Margaret Elrington Norman N. Greenwood John D. Kennedy J.Derek Woollins |
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| Affiliation: | Department of Inorganic and Structural Chemistry, The University of Leeds, Leeds LS2 9JT, England |
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| Abstract: | The new ruthenaundecaborane [(PPh3)2RuB10H8 (OEt)2] may be considered as an eleven-vertex member of a previously unrecognised series of metallaboranes which are formally derived by the single capping of an arachno-type (rather than a nido-type) cluster geometry with a metal centre which can be thought of as contributing four orbitals to the cluster bonding schemes. |
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