Spectral and electrochemical studies on oxoisothiocyanatobis(pyrrolidinyldithiocarbamato)molybdenum(V) |
| |
| Authors: | K.S. Nagaraja M.R. Udupa |
| |
| Affiliation: | Department of Chemistry, Indian Institute of Technology, Madras 600 036, India |
| |
| Abstract: | The complex, oxoisothiocyanatobis(pyrrolidinyldithiocarbamato)molybdenum(V), MoO(NCS) (pyrroldtc)2 was prepared. The IR spectra of the complex suggest that the thiocyanate group is attached through nitrogen and the presence of MoO3+ moiety. The voltammograms of the complex in acetonitrile exhibited a pronounced cathodic wave at ?0.23 V vs S.C.E. which was attributed to Mo(V)/Mo(IV) couple. The magnetic, epr and electrochemical studies indicate that the compound is mononuclear and molybdenum is in +5 oxidation state. |
| |
| Keywords: | Author to whom correspondence should be addressed. |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
