Studies of the reactions of thiocyanate ion with pentammine dinitrogen ruthenium(II) dibromide at different temperatures |
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| Authors: | SKS Yadav UC Agarwala |
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| Institution: | Department of Chemistry, Indian Institute of Technology, Kanpur 208 016, India |
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| Abstract: | The salts of the linkage isomers of thiocyanatopentammineruthenium(III) Ru(NH3)5(NCS)]2+, Ru(NH3)5(SCN)]2+ and dithiocyanatotetrammineruthenium(III) Ru(NH3)4(NCS)2]+ along with those of tetrathiocyanatodiammineruthenate(III) Ru(NH3)2(SCN)4]? have been synthesized. The insoluble polymeric complex Ru(NH3)2(SCN)2]n has also been prepared. The compounds have been characterized by chemical analyses, spectral (IR, UV and visible), magnetic susceptibility, conductivity, cyclic voltammetry and chromatography studies. |
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| Keywords: | Author to whom correspondence should be addressed |
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