Unusual metalloporphyrins : thorium and uranium complexes of octaethylporphyrin. |
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| Authors: | Alain Dormond Boussad Belkalem Roger Guilard |
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| Affiliation: | Laboratoire de Synthèse et d''Electrosynthèse Organométallique associé au C.N.R.S. (LA 33), Faculté des Sciences “Gabriel”, 6, Bd Gabriel, 21100 Dijon, France |
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| Abstract: | The action of thorium or uranium tetrachloride with octaethylporphyrin [(oep)H2] affords the dichlorometal (IV) complexes [M(IV)(oep)Cl2, Ln] (M(IV) = Th or U, L = benzonitrile, tetrahydrofuran or pyridine). Spectral properties of these complexes are in good agreement with a cis octa-coordination. |
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| Keywords: | Author for correspondence. |
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