Fluoride complexes of the alkali metal ions |
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| Authors: | CB Chan NH Tioh GT Hefter |
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| Institution: | Chemistry Department, University of Malaya, Kuala Lumpur 22-11, Malaysia;School of Mathematical and Physical Sciences, Murdoch University, Murdoch, W.A. 6150, Australia |
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| Abstract: | Measurements by fluoride ion-selective electrode potentiometry on the very weak monofluoride complexes of the alkali metal ions in aqueous solution at 25°C and an ionic strength of 1M indicate their stability constants lie in the order Li+ > Na+ > K+ > Rb+ ? Cs+. Data at varying ionic strengths and temperatures were used to calculate infinite dilution stability constants and enthalpies and entropies of complexation for LiF and NaF. |
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| Keywords: | Author to whom correspondence should be addressed |
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