Alkyl complexes of palladium(II) with trimethylphosphine and 1,2-bis-(dimethylphosphino)ethane ligands |
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| Authors: | Robert Tooze Kwok W Chiu Geoffrey Wilkinson |
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| Institution: | Chemistry Department, Imperial College, London SW7 2AY, England |
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| Abstract: | A number of neutral, mononuclear dialkylpalladium(II) tertiary phosphine complexes of geneal formula cis or trans-PdR2(PMe3)2 and cis-PdR2 (dmpe) dmpe = 1,2-bis(dimethylphosphino)ethane], R = Me, CH2Ph, CH2CMe2Ph, CH2SiMe3 have been obtained by interaction of magnesium reagents with palladium(II) acetate or trans-Pd(O2CMe)2(PMe3)2. |
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| Keywords: | Author to whom correspondence should be addressed |
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