On the tri-n-octylammonium chlorocomplexes of Sn(IV) in benzene solution |
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| Authors: | Claus Fischer Harald Wagner Vladimir V Bagreev |
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| Institution: | Central Institute of Solid State Physics and Material Research, Academy of Sciences of the GDR, 8027 Dresden, Helmholtzstraße 20, GDR;V.I. Vernadsky Institute of Geochemistry and Analytical Chemistry, USSR Academy of Sciences, Moscow, U.S.S.R. |
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| Abstract: | Extracts with tri-n-octylammonium chlorocomplexes of Sn(IV) of various compositions, included the N-deuterated compounds, were prepared and investigated by IR spectroscopy and conductivity measurements. Three Sn(IV) complexes were found: (TOAH+)2SnCl62? (2:1-complex), TOAH+SnCl5? (1:1-complex) and a complex with the stoichiometric ratio TOA:Sn(IV) > 2. The cation of the latter contains the groups (TOAH…Cl…HTOA)+ and TOAH+ and that species is supposed to be a 3:1-complex (TOAH…Cl…HTOA)+TOAH+SnCl62?. |
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| Keywords: | Author to whom correspondence should be addressed |
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