a State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, P.R. China
b Department of Chemistry, Okayama University of Science, 1-1 Ridai-cho, Okayama 700, Japan
Abstract:
A series of isomalononitrile dithiolato palladium complexes, (PPh3)2Pd(1-mnt) (1), [P(OPh)3]2Pd(i-mnt) (2), (PPh3)(py)Pd(i-mnt)·CH3CN (4), (Et4N)2Pd(i-mnt)2 (4) and (Ph4As)2Pd(i-mnt)2 (5) were synthesized and characterized by elemental analysis and IR spectroscopy. The reaction between (Et4N)2Pd(i-mnt)2 (4) and (Et4N)2WS4 gave a mixed metal cluster (Et4N)2WS4Pd(i-mnt) (6). The crystallographically determined structures of 1 and 6 are reported.