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Synthesis of Al–Cr decagonal quasicrystal nanoparticles and their temperature of phase transformation to stable crystal phase
Authors:Osamu Kido  Mami Kurumada  Katsuya Kamitsuji  Toshiaki Tanigaki  Takeshi Sato  Yuki Kimura  Hitoshi Suzuki  Yoshio Saito  Chihiro Kaito
Institution:aDepartment of Nanophysics in Frontier Projects, Ritsumeikan University, Nojihigashi 1-1-1, Kusatsu-shi, Shiga 525-0055, Japan;bDepartment of Electronics and Information Science, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku 606-8585, Japan
Abstract:The synthesis of Al–Cr single quasicrystal (QC) nanoparticles of the decagonal phase was achieved by introducing an advanced gas flow evaporation method. By obtaining successive electron diffraction patterns for single-QC nanoparticles, the phase transformation temperature of a single-QC nanoparticle was determined to be 700 °C. It was also determined that part of the QC nanoparticle decomposed into hex-Al8Cr5 and Al during the phase transformation. Since the grain growth did not occur during the phase transformation in the present experiment, the inherent phase transformation temperature could be measured.
Keywords:Electron diffraction  Aluminum alloys  Nanocrystalline materials  Quasicrystals  Phase transformations
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