Synthesis and structures of 1,1"-dialkyl-3,3"-bidiaziridines |
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| Authors: | Petukhova V. Yu. Kuznetzov V. V. Shevtsov A. V. Strelenko Yu. A. Makhova N. N. Lyssenko K. A. Antipin M. Yu. |
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| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119992 Moscow, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | First representatives of 3,3"-bidiaziridines, viz., 1,1"-dialkyl-3,3"-bidiaziridines, were synthesized and isolated as mixtures of two diastereomers. In the case of Alk = Me, the diastereomers were separated. It was demonstrated by nuclear Overhauser effect experiments and X-ray diffraction analysis that the diastereomers are the racemate (rac-1R*,2R*,3S*,1"R*,2"R*,3"S*) and the meso-form (1S*,2S*,3R*,1"R*,2"R*,3"S*). |
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| Keywords: | 3,3" -bidiaziridines 1,1" -dialkyl-3,3" -bidiaziridines pHopt diastereomers X-ray diffraction analysis |
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